C4H8O2
CAS Registry Number: 5703-46-8
ACX Registry Number:
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Synonyms for dioxane :
dioxane

WARNINGS which mention dioxane:

From CONVERSION OF METHYL KETONES INTO TERMINAL ACETYLENES: ETHYNYLFERROCENE, Collective Volume 9 p. 411, Annual Volume 73 p. 262

CAUTION: dioxane is a cancer suspect agent and a flammable liquid

From CATALYST, RANEY NICKEL, W-2, Collective Volume 3 p. 181, Annual Volume 21 p. 15

Caution. Do not use nickel in dioxane above 210°; the dioxane may react almost explosively with hydrogen and Raney nickel above this temperature


Preps in which dioxane appears:

Preparation of Enantioenriched Homoallylic Primary Amines
Submitted by: José C. González-Gómez, Francisco Foubelo, and Miguel Yus
Published in Annual Volume 89 p. 88

CATALYTIC ENANTIOSELECTIVE BORANE REDUCTION OF BENZYL OXIMES: PREPARATION OF (S)-1-PYRIDIN-3-YL-ETHYLAMINE BIS HYDROCHLORIDE
Submitted by: Kun Huang and Margarita Ortiz-Marciales
Published in Annual Volume 87 p. 36

A PRACTICAL PROCEDURE FOR CARBONYL α-OXIDATION: SYNTHESIS OF (2-BENZOYLOXY)-1,4-CYCLOHEXANEDIONE MONO-ETHYLENE KETAL
Submitted by: Teyrnon C. Jones and Nicholas C. O. Tomkinson
Published in Collective Volume 11 p. 70, Annual Volume 84 p. 233

1,4-DIOXENE
Submitted by: Matthew M. Kreilein, James C. Eppich, and Leo A. Paquette
Published in Collective Volume 11 p. 850, Annual Volume 82 p. 99

SYNTHESIS OF 1,2:5,6-DIANHYDRO-3,4-O-ISOPROPYLIDENE-L-MANNITOL
Submitted by: David A. Nugiel, Kim Jacobs, A. Christine Tabaka, and Chris A. Teleha
Published in Collective Volume 11 p. 164, Annual Volume 81 p. 140

(R)-3-PHENYLCYCLOHEXANONE
Submitted by: Tamio Hayashi, Makoto Takahashi, Yoshiaki Takaya, and Masamichi Ogasawara
Published in Collective Volume 10 p. 609, Annual Volume 79 p. 84

ASYMMETRIC SYNTHESIS OF (M)-2-HYDROXYMETHYL-1-(2-HYDROXY-4,6-DIMETHYLPHENYL)NAPHTHALENE VIA A CONFIGURATIONALLY UNSTABLE BIARYL LACTONE
Submitted by: Gerhard Bringmann, Matthias Breuning, Petra Henschel, and Jürgen Hinrichs
Published in Collective Volume 10 p. 448, Annual Volume 79 p. 72

PHOTOCHEMICAL SYNTHESIS OF BICYCLO[1.1.1]PENTANE-1,3-DICARBOXYLIC ACID
Submitted by: Michael D. Levin, Piotr Kaszynski, and Josef Michl
Published in Collective Volume 10 p. 86, Annual Volume 77 p. 249

ASYMMETRIC SYNTHESIS OF α-AMINO ACIDS BY THE ALKYLATION OF PSEUDOEPHEDRINE GLYCINAMIDE: L-ALLYLGLYCINE AND N-BOC-L-ALLYLGLYCINE
Submitted by: Andrew G. Myers and James L. Gleason
Published in Collective Volume 10 p. 12, Annual Volume 76 p. 57

4-METHOXY-4'-NITROBIPHENYL
Submitted by: J. K. Stille, Antonio M. Echavarren, Robert M. Williams, and James A. Hendrix
Published in Collective Volume 9 p. 553, Annual Volume 71 p. 97

CONVERSION OF METHYL KETONES INTO TERMINAL ACETYLENES: ETHYNYLFERROCENE
Submitted by: Johann Polin and Herwig Schottenberger
Published in Collective Volume 9 p. 411, Annual Volume 73 p. 262

CYCLOPROPANATION USING AN IRON-CONTAINING METHYLENE TRANSFER REAGENT: 1,1-DIPHENYLCYCLOPROPANE
Submitted by: Matthew N. Mattson, Edward J. O'Connor, and Paul Helquist
Published in Collective Volume 9 p. 372, Annual Volume 70 p. 177

1,1,-DIMETHYLETHYL (S)- OR (R)-4-FORMYL-2,2-DIMETHYL-3-OXAZOLIDINECARBOXYLATE: A USEFUL SERINAL DERIVATIVE
Submitted by: Philip Garner and Jung Min Park
Published in Collective Volume 9 p. 300, Annual Volume 70 p. 18

DIETHYL (2S,3R)-2-(N-tert-BUTOXYCARBONYL)AMINO- 3-HYDROXYSUCCINATE
Submitted by: Seiki Saito, Kanji Komada, and Toshio Moriwake
Published in Collective Volume 9 p. 220, Annual Volume 73 p. 184

(+)-(2R,8aR)-[(8,8-DIMETHOXYCAMPHORYL)SULFONYL]OXAZIRIDINE AND (+)-(2R,8aR)-[(8,8-DICHLOROCAMPHORYL)SULFONYL]OXAZIRIDINE
Submitted by: Bang-Chi Chen, Christopher K. Murphy, Anil Kumar, R. Thimma Reddy, Charles Clark, Ping Zhou, Bryan M. Lewis, Dinesh Gala, Ingrid Mergelsberg, Dominik Scherer, Joseph Buckley, Donald DiBenedetto, and Franklin A. Davis
Published in Collective Volume 9 p. 212, Annual Volume 73 p. 159

(−)-(1S,4R)-CAMPHANOYL CHLORIDE
Submitted by: Hans Gerlach, Dag Kappes, Robert K. Boeckman, and Graham N. Maw
Published in Collective Volume 9 p. 151, Annual Volume 71 p. 48

α-UNSUBSTITUTED γ,δ-UNSATURATED ALDEHYDES BY CLAISEN REARRANGEMENT: 3-PHENYL-4-PENTENAL
Submitted by: Dennis E. Vogel and George H. Büchi
Published in Collective Volume 8 p. 536, Annual Volume 66 p. 29

(S)-N,N-DIMETHYL-N'-(1-tert-BUTOXY-3-METHYL-2-BUTYL)FORMAMIDINE
Submitted by: Daniel A. Dickman, Michael Boes, and Albert I. Meyers
Published in Collective Volume 8 p. 204, Annual Volume 67 p. 52

DIALKOXYACETYLENES: DI-tert-BUTOXYETHYNE, A VALUABLE SYNTHETIC INTERMEDIATE
Submitted by: Anna Bou, Miquel A. Pericàs, Antoni Riera, and Fèlix Serratosa
Published in Collective Volume 8 p. 161, Annual Volume 65 p. 68

4,13-DIAZA-18-CROWN-6
Submitted by: Vincent J. Gatto, Steven R. Miller, and George W. Gokel
Published in Collective Volume 8 p. 152, Annual Volume 68 p. 227

SPIRO[5.7]TRIDECA-1,4-DIEN-3-ONE
Submitted by: Vinayak V. Kane and Maitland Jones, Jr
Published in Collective Volume 7 p. 473, Annual Volume 61 p. 129

METHYLENE KETONES AND ALDEHYDES BY SIMPLE, DIRECT METHYLENE TRANSFER: 2-METHYLENE-1-OXO-1,2,3,4-TETRAHYDRONAPHTHALENE
Submitted by: Jean-Louis Gras
Published in Collective Volume 7 p. 332, Annual Volume 60 p. 88

ONE-STEP HOMOLOGATION OF ACETYLENES TO ALLENES: 4-HYDROXYNONA-1,2-DIENE
Submitted by: Pierre Crabbé, Bahman Nassim, and Maria-Teresa Robert-Lopes
Published in Collective Volume 7 p. 276, Annual Volume 63 p. 203

N-tert-BUTOXYCARBONYL-l-PHENYLALANINE
Submitted by: William J. Paleveda, Frederick W. Holly, and Daniel F. Veber
Published in Collective Volume 7 p. 75, Annual Volume 63 p. 171

tert-BUTOXYCARBONYLATION OF AMINO ACIDS AND THEIR DERIVATIVES: N-tert-BUTOXYCARBONYL-l-PHENYLALANINE
Submitted by: Oskar Keller, Walter E. Keller, Gert van Look, and Gernot Wersin
Published in Collective Volume 7 p. 70, Annual Volume 63 p. 160

p-TOLYLSULFONYLDIAZOMETHANE
Submitted by: A. M. van Leusen and J. Strating
Published in Collective Volume 6 p. 981, Annual Volume 57 p. 95

REARRANGEMENT OF BRIDGEHEAD ALCOHOLS TO POLYCYCLIC KETONES BY FRAGMENTATION-CYCLIZATION: 4-PROTOADAMANTANONE (TRICYCLO-[4.3.1.03,8]DECAN-4-ONE)
Submitted by: Zdenko Majerski and Zdenko Hameršak
Published in Collective Volume 6 p. 958, Annual Volume 59 p. 147

POLYMERIC CARBODIIMIDE. PREPARATION
Submitted by: Ned M. Weinshenker, Chah M. Shen, and Jack Y. Wong
Published in Collective Volume 6 p. 951, Annual Volume 56 p. 95

4-PHENYL-1,2,4-TRIAZOLINE-3,5-DIONE
Submitted by: R. C. Cookson, S. S. Gupte, I. D. R. Stevens, and C. T. Watts
Published in Collective Volume 6 p. 936, Annual Volume 51 p. 121

PENTAFLUOROPHENYLCOPPER TETRAMER, A REAGENT FOR SYNTHESIS OF FLUORINATED AROMATIC COMPOUNDS
Submitted by: Allan Cairncross, William A. Sheppard, and Edward Wonchoba
Published in Collective Volume 6 p. 875, Annual Volume 59 p. 122

1,6-OXIDO[10]ANNULENE
Submitted by: E. Vogel, W. Klug, and A. Breuer
Published in Collective Volume 6 p. 862, Annual Volume 55 p. 86

HIGHLY REACTIVE MAGNESIUM FOR THE PREPARATION OF GRIGNARD REAGENTS: 1-NORBORNANECARBOXYLIC ACID
Submitted by: Reuben D. Rieke, Stephen E. Bales, Phillip M. Hudnall, Timothy P. Burns, and Graham S. Poindexter
Published in Collective Volume 6 p. 845, Annual Volume 59 p. 85

FORMATION AND PHOTOCHEMICAL WOLFF REARRANGEMENT OF CYCLIC α-DIAZO KETONES: D-NORANDROST-5-EN-3β-OL-16-CARBOXYLIC ACIDS
Submitted by: Thomas N. Wheeler and J. Meinwald
Published in Collective Volume 6 p. 840, Annual Volume 52 p. 53

NUCLEOPHILIC ACYLATION WITH DISODIUM TETRACARBONYLFERRATE: METHYL 7-OXOHEPTANOATE AND METHYL 7-OXOÖCTANOATE
Submitted by: Richard G. Finke, and Thomas N. Sorrell
Published in Collective Volume 6 p. 807, Annual Volume 59 p. 102

OXYMERCURATION-REDUCTION: ALCOHOLS FROM OLEFINS: 1-METHYLCYCLOHEXANOL
Submitted by: J. M. Jerkunica and T. G. Traylor
Published in Collective Volume 6 p. 766, Annual Volume 53 p. 94

1,6-METHANO[10]ANNULENE
Submitted by: E. Vogel, W. Klug, and A. Breuer
Published in Collective Volume 6 p. 731, Annual Volume 54 p. 11

TRICHLOROMETHYL CHLOROFORMATE AS A PHOSGENE EQUIVALENT: 3-ISOCYANATOPROPANOYL CHLORIDE
Submitted by: Keisuke Kurita and Yoshio Iwakura
Published in Collective Volume 6 p. 715, Annual Volume 59 p. 195

1,2-DIMETHYLCYCLOBUTENES BY REDUCTIVE RING-CONTRACTION OF SULFOLANES: cis-7,8-DIMETHYLBICYCLO[4.2.0]OCT-7-ENE
Submitted by: James M. Photis and Leo A. Paquette
Published in Collective Volume 6 p. 482, Annual Volume 57 p. 53

18-CROWN-6
Submitted by: George W. Gokel, Donald J. Cram, Charles L. Liotta, Henry P. Harris, and Fred L. Cook
Published in Collective Volume 6 p. 301, Annual Volume 57 p. 30

m-CHLOROPERBENZOIC ACID
Submitted by: Richard N. McDonald, Richard N. Steppel, and James E. Dorsey
Published in Collective Volume 6 p. 276, Annual Volume 50 p. 15

REMOVAL OF Nα-BENZYLOXYCARBONYL GROUPS FROM SULFUR-CONTAINING PEPTIDES BY CATALYTIC HYDROGENATION IN LIQUID AMMONIA: O-tert-BUTYL-L-SERYL-S-tert-BUTYL-L-CYSTEINE tert-BUTYL ESTER
Submitted by: Arthur M. Felix, Manuel H. Jimenz, and Johannes Meienhofer
Published in Collective Volume 6 p. 252, Annual Volume 59 p. 159

A NEW REAGENT FOR tert-BUTOXYCARBONYLATION: 2-tert-BUTOXYCARBONYLOXYIMINO-2-PHENYLACETONITRILE
Submitted by: Masumi Itoh, Daijiro Hagiwara, and Takashi Kamiya
Published in Collective Volume 6 p. 199, Annual Volume 59 p. 95

BICYCLO[1.1.0]BUTANE
Submitted by: Gary M. Lampman and James C. Aumiller
Published in Collective Volume 6 p. 133, Annual Volume 51 p. 55

REDUCTION OF KETONES BY USE OF THE TOSYLHYDRAZONE DERIVATIVES: ANDROSTAN-17 β-OL
Submitted by: L. Caglioti
Published in Collective Volume 6 p. 62, Annual Volume 52 p. 122

2,4,6-TRIPHENYLPHENOXYL
Submitted by: K. Dimroth, A. Berndt, H. Perst, and C. Reichardt
Published in Collective Volume 5 p. 1130, Annual Volume 49 p. 116

2,4,6-TRIMETHYLPYRYLIUM TRIFLUOROMETHANESULFONATE
Submitted by: A. T. Balaban and A. J. Boulton
Published in Collective Volume 5 p. 1114, Annual Volume p.

1,2,3,4-TETRAPHENYLNAPHTHALENE
Submitted by: Louis F. Fieser and Makhluf J. Haddadin
Published in Collective Volume 5 p. 1037, Annual Volume 46 p. 107

3-PHENYLSYDNONE
Submitted by: Charles J. Thoman and Denys J. Voaden
Published in Collective Volume 5 p. 962, Annual Volume 45 p. 96

Δ1(9)-OCTALONE-2
Submitted by: Robert L. Augustine and Joseph A. Caputo
Published in Collective Volume 5 p. 869, Annual Volume 45 p. 80

METHYL PHENYL SULFOXIDE
Submitted by: Carl R. Johnson and Jeffrey E. Keiser
Published in Collective Volume 5 p. 791, Annual Volume 46 p. 78

2-METHYL-1,3-CYCLOHEXANEDIONE
Submitted by: A. B. Mekler, S. Ramachandran, S. Swaminathan, and Melvin S. Newman
Published in Collective Volume 5 p. 743, Annual Volume 41 p. 56

N-IODOSUCCINIMIDE
Submitted by: W. R. Benson, E. T. McBee, and L. Rand
Published in Collective Volume 5 p. 663, Annual Volume 42 p. 73

1,1-DIPHENYLCYCLOPROPANE
Submitted by: M. J. Jorgenson and A. F. Thacher
Published in Collective Volume 5 p. 509, Annual Volume 48 p. 75

trans-4,4'-DIMETHOXYSTILBENE
Submitted by: J. W. A. Findlay and A. B. Turner
Published in Collective Volume 5 p. 428, Annual Volume 49 p. 53

3β-ACETOXYETIENIC ACID
Submitted by: J. Staunton and E. J. Eisenbraun
Published in Collective Volume 5 p. 8, Annual Volume 42 p. 4

SODIUM β-STYRENESULFONATE AND β-STYRENESULFONYL CHLORIDE
Submitted by: Christian S. Rondestvedt, Jr and F. G. Bordwell
Published in Collective Volume 4 p. 846, Annual Volume 34 p. 85

γ-PHENYLALLYLSUCCINIC ACID
Submitted by: Christian S. Rondestvedt, Jr
Published in Collective Volume 4 p. 766, Annual Volume 31 p. 85

METHYL γ-METHYL-γ-NITROVALERATE
Submitted by: R. B. Moffett
Published in Collective Volume 4 p. 652, Annual Volume 32 p. 86

1-METHYLISOQUINOLINE
Submitted by: J. Weinstock and V. Boekelheide
Published in Collective Volume 4 p. 641, Annual Volume 38 p. 58

p-METHOXYPHENYLACETONITRILE
Submitted by: Kurt Rorig, J. Derland Johnston, Robert W. Hamilton, and Thomas J. Telinski
Published in Collective Volume 4 p. 576, Annual Volume 36 p. 50

DI-tert-BUTYL MALONATE
Submitted by: Allen L. McCloskey, Gunther S. Fonken, Rudolph W. Kluiber, William S. Johnson, and Chittaranjan Raha
Published in Collective Volume 4 p. 261, Annual Volume 34 p. 26

1,2-CYCLOHEXANEDIONE DIOXIME
Submitted by: Clifford C. Hach, Charles V. Banks, and Harvey Diehl
Published in Collective Volume 4 p. 229, Annual Volume 32 p. 35

p-CHLOROPHENYL SALICYLATE
Submitted by: Norman G. Gaylord and P. M. Kamath
Published in Collective Volume 4 p. 178, Annual Volume 32 p. 25

BENZOYLCHOLINE IODIDE AND CHLORIDE
Submitted by: A. H. Ford-Moore
Published in Collective Volume 4 p. 84, Annual Volume 30 p. 10

2-AMINO-4-ANILINO-6-(CHLOROMETHYL)-s-TRIAZINE
Submitted by: C. G. Overberger and Francis W. Michelotti
Published in Collective Volume 4 p. 29, Annual Volume 38 p. 1

dl-VALINE
Submitted by: C. S. Marvel
Published in Collective Volume 3 p. 848, Annual Volume 20 p. 106

1-PHENYL-3-AMINO-5-PYRAZOLONE
Submitted by: H. D. Porter and A. Weissberger
Published in Collective Volume 3 p. 708, Annual Volume 28 p. 87

NAPHTHORESORCINOL
Submitted by: Karl Meyer and Henry S. Bloch
Published in Collective Volume 3 p. 637, Annual Volume 25 p. 73

MONOPERPHTHALIC ACID
Submitted by: Horst Böhme
Published in Collective Volume 3 p. 619, Annual Volume 20 p. 70

LINOLENIC ACID
Submitted by: J. W. McCutcheon
Published in Collective Volume 3 p. 531, Annual Volume 22 p. 82

ISATOIC ANHYDRIDE
Submitted by: E. C. Wagner and Marion F. Fegley
Published in Collective Volume 3 p. 488, Annual Volume 27 p. 45

GLYOXAL BISULFITE
Submitted by: Anthony R. Ronzio and T. D. Waugh
Published in Collective Volume 3 p. 438, Annual Volume 24 p. 61

β,β-DIMETHYLACRYLIC ACID
Submitted by: Lee Irvin Smith, W. W. Prichard, and Leo J. Spillane
Published in Collective Volume 3 p. 302, Annual Volume 23 p. 27

2,6-DIMETHOXYBENZONITRILE
Submitted by: Alfred Russell and W. G. Tebbens
Published in Collective Volume 3 p. 293, Annual Volume 22 p. 35

CATALYST, RANEY NICKEL, W-2
Submitted by: Ralph Mozingo
Published in Collective Volume 3 p. 181, Annual Volume 21 p. 15

tert-BUTYLAMINE
Submitted by: Kenneth N. Campbell, Armiger H. Sommers, Barbara K. Campbell, Lee Irvin Smith, Oliver H. Emerson, D. E. Pearson, J. F. Baxter, and K. N. Carter
Published in Collective Volume 3 p. 148, Annual Volume 27 p. 12

PHENYLGLYOXAL
Submitted by: H. A. Riley and A. R. Gray
Published in Collective Volume 2 p. 509, Annual Volume 15 p. 67

2,4-DINITROPHENYLHYDRAZINE
Submitted by: C. F. H. Allen
Published in Collective Volume 2 p. 228, Annual Volume 13 p. 36

BENZOHYDROXAMIC ACID
Submitted by: C. R. Hauser and W. B. Renfrow, Jr
Published in Collective Volume 2 p. 67, Annual Volume 19 p. 15